Why does lithium show anomalous behavior?

Fluorosis disease is caused due to the reaction of ...... with excess of fluoride in the body.

The useful by-products obtained in the $Solvay$ process of manufacturing sodium carbonate are:

Given below are two statements: one is labelled as Assertion $A$ and the other is labelled as Reason $R:$
Assertion $A:$ Metallic sodium dissolves in liquid ammonia giving a deep blue solution,which is paramagnetic.
Reason $R:$ The deep blue solution is due to the formation of amide.
In the light of the above statements,choose the correct answer from the options given below:

The compound which is not associated with the Solvay ammonia process for the production of $Na_2CO_3$ is:

Given below are two statements: one is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: $LiF$ is sparingly soluble in water.
Reason $R$: The ionic radius of $Li^{+}$ ion is smallest among its group members,hence it has the least hydration enthalpy.
In the light of the above statements,choose the most appropriate answer from the options given below.